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71.
Pollen and macrofossil analyses of a sediment core from Beaver Pond (60° 37′ 14″ N, 154° 19′ W, 579 m a.s.l.) reveal a record of regional and local postglacial vegetation change in south‐western Alaska. The chronology is based on five AMS (accelerator mass spectrometry) 14C ages obtained from terrestrial plant macrofossils. Pollen and macrofossil records suggest that open herb and shrub tundra with e.g. Poaceae, Cyperaceae, Artemisia, Vaccinium and Salix prevailed on the landscape before ca. 14 000 cal a BP. The shift from herb‐ to shrub‐dominated tundra (Salix, subsequent Betula expansion) possibly reflects climatic warming at the beginning of the Bølling period at ca. 14 700–14 500 and around 13 500 cal a BP. Vegetation (Betula shrub tundra) remained relatively stable until the early Holocene. Macrofossil influx estimates provide evidence for greater biomass in Betula shrub tundra during the early postglacial period than today. Charcoal accumulation rates suggest tundra fire activity was probably greater from ca. 12 500 to 10 500 cal a BP, similar to results from elsewhere in Alaska. The pollen and macrofossil records of Beaver Pond suggest the prevalence of low shrub tundra (shrub Betula, Betula nana, Vaccinium, Ledum palustre, Ericaceae) and tall shrub tundra (Alnus viridis ssp. crispa, Salix) between 10 000 and 4000 cal a BP. This Holocene vegetation type is comparable with that of the modern treeless wet and moist tundra in south‐western Alaska. The expansion of Picea glauca occurred ~4000 cal a BP, much later than that of A. viridis (ssp. crispa), whereas in central and eastern Alaska Picea glauca expanded prior to or coincident with Alnus (viridis). At sites located only 200–400 km north‐east of Beaver Pond (Farewell and Wien lakes), Picea glauca and Betula forests expanded 8000–6000 cal a BP. Unfavourable climatic conditions and soil properties may have inhibited the expansion and establishment of Picea across south‐west Alaska during the mid and late Holocene. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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Siderophores play an important role in biological iron acquisition in iron-limited aquatic systems. While it is widely accepted that the solubilization of iron-bearing mineral phases is a key function of siderophores, the mechanism of siderophore-promoted mineral dissolution in aquatic systems is largely unknown. In this study, we investigated the effect of siderophores (desferrioxamine B (DFOB) and aerobactin) on light-induced dissolution of goethite and lepidocrocite in the presence or absence of oxalate in aerated and deaerated suspensions at pH 6. For the irradiated two-ligand system (oxalate/siderophore), the experimental results suggest that oxalate acts as the electron donor for the formation of surface Fe(II), and the siderophore acts as an efficient shuttle for the transfer of surface Fe(II) into solution. Furthermore, even in the absence of an electron donor such as oxalate, both DFOB and aerobactin accelerated the light-induced dissolution of lepidocrocite as compared to the thermal dissolution. Experiments with dissolved Fe(III)–DFOB and Fe(III)–aerobactin complexes suggest that this enhancing effect is not due to photolysis of corresponding surface complexes but to efficient transfer of reduced surface Fe(II) into solution, where surface Fe(II) may be formed, e.g., through photolysis of surface Fe(III)–hydroxo groups. Based on this study, we conclude that the interplay of light and siderophores may play a key role in the dissolution of colloidal iron(III) (hydr)oxides in marine systems, particularly in the presence of efficient electron donors.  相似文献   
73.
The metamorphic Raspas Complex of southwest Ecuador consists of high-pressure mafic, ultramafic, and sedimentary rocks. The Lu–Hf ages of a blueschist, a metapelite, and an eclogite overlap at around 130 Ma and date high-pressure garnet growth. Peak metamorphic conditions in the eclogites reached 1.8 GPa at 600°C, corresponding to a maximum burial depth of ~60 km. The geochemical signatures of the eclogites suggest that their protoliths were typical mid-ocean ridge basalts (MORB), whereas the blueschists exhibit seamount-like characteristics, and the eclogite-facies peridotites seem to represent depleted, MORB-source mantle. That these rocks were subjected to similar peak PT conditions contemporaneously suggests that they were subducted together as an essentially complete section within the slab. We suggest that this section became dismembered from the slab during burial at great depth—perhaps as a consequence of scraping off the seamounts. The spatially close association of MORB-type eclogite, seamount-type blueschist, serpentinized peridotite, and metasediments points to an exhumed high-pressure ophiolite sequence.  相似文献   
74.
Preservation of wing membranes in pterosaurs is only reported from a few localities in the world, namely from the Karatau Hills, Kazakhstan (Upper Jurassic), from the Solnhofen Lithographic Limestone, Germany (Upper Jurassic), the Daohugou Beds of China (Upper Jurassic or Lower Cretaceous) and the Crato and Santana Formations, Chapada do Araraipe, NE Brazil (Lower Cretaceous).  相似文献   
75.
This article explores how the causes and impacts of a flood event as perceived by local people shape immediate responses and future mitigation efforts in mountainous northwest Vietnam. Local flood perception is contrasted with scientific perspectives to determine whether a singular flood event will trigger adjustments in mitigation strategies in an otherwise rarely flood-affected area. We present findings from interdisciplinary research drawing on both socioeconomic and biophysical data. Evidence suggests that individual farmers?? willingness to engage in flood mitigation is curbed by the common perception that flooding is caused by the interplay of a bundle of external factors, with climatic factors and water management failures being the most prominent ones. Most farmers did not link the severity of flooding to existing land use systems, thus underlining the lack of a sense of personal responsibility among farmers for flood mitigation measures. We conclude that local governments cannot depend on there being a sufficient degree of intrinsic motivation among farmers to make them implement soil conservation techniques to mitigate future flooding. Policy makers will need to design measures to raise farmers?? awareness of the complex interplay between land use and hydrology and to enhance collective action in soil conservation by providing appropriate incentives and implementing coherent long-term strategies.  相似文献   
76.
Competitive interactions between silicate and phosphate at ligand exchange sites in the sediment surface layer may increase the release of phosphorus (P) from the sediment into the water column. In this study, the role of silicon (Si) in the release of P from the sediment surface layer was studied in a marine estuarine environment, the Bay of Brest, with the aid of a sequential sediment fractionation procedure developed for P, and the addition of inorganic or diatom-bound Si to surface sediment samples in vitro. The potentially mobile pools of P in the surface sediment (loosely bound P + Fe/Al-bound-P) amounted to 5.0 μmol g−1 dry sed., 42% of the total extractable and 33% of the total amount of P in the sediment, while the similarly extracted pools of Si were bigger (ca. 20 μmol g−1 dry sed., 50% of the total extractable Si). Additions of inorganic Si increased the concentration of dissolved P in the sediment interstitial water in a bottle experiment, and the addition of both inorganic Si and cultivated diatoms to intact sediment cores increased the outward flux of dissolved P. Model calculations based on the regression equation from the bottle experiment and Si and P water column data showed that the sedimentation of spring diatoms could cause Si pulses to the sediment which would produce a P flux to the water column of ca. 44 μmol m−2 d−1. Field data from the bay show that in spring, decreases in P and Si and an increase in chl a due to diatom production are often followed by a small separate P peak which may be caused by Si-induced P fluxes from the sediment surface.  相似文献   
77.
Recent sedimentological and palynological research on subfossil Holocene banded sediments from the Severn Estuary Levels suggested seasonality of deposition, registered by variations in mineral grain‐size and pollen assemblages between different parts of the bands. Here we provide data that strengthen this interpretation from sampling of modern sediments and pollen deposition on an active mudflat and saltmarsh on the margin of the Severn Estuary, and comparison with a vegetation survey and contemporary records of climate, river and tidal regimes. The results of grain‐size analysis indicate deposition of comparatively coarse‐grained silts during the relatively cool and windy conditions of winter and comparatively fine‐grained sediments during relatively warm and calm summer months. Pollen analysis demonstrates the significance of long‐term storage of pollen grains and fern spores in the estuarine waterbody, superimposed on which seasonal variations in pollen inputs from local and regional vegetation remain detectable. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   
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